Use the bond enthalpy data in Table 2.7 to calculate the enthalpy of formation for NF 3
Question:
Use the bond enthalpy data in Table 2.7 to calculate the enthalpy of formation for NF3 and NCl3. Explain why NF3 is thermodynamically stable whereas NCl3 is unstable and reactive.
Table 2.7.
Transcribed Image Text:
TABLE 2.7 Mean bond enthalpies, B/(kJ mol-¹)* H N 436 412 H с N O F LL 565 431 Br 366 1 299 338 322 (1) U S P 388 Si 463 318 с 348 (1) 612 (2) 837 (3) 518 (a) 305 (1) 613 (2) 890 (3) 360 (1) 743 (2) 484 338 276 238 259 163 (1) 409 (2) 946 (3) 157 270 200 464 0 146 (1) 497 (2) 185 203 523 407 560 (2) 466 F 155 254 343 CI 242 219 210 250 Br 193 178 212 I 151 S 264 P 201 480 (3) SI 226
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To calculate the enthalpy of formation for NF3 and NCl3 using bond enthalpy data we need to use the following equation Hf Hbonds broken Hbonds formed ...View the full answer
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Related Book For
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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