Volcanoes and deep sea hydrothermal vents are both associated with sulfur-rich environments. Mount Etna is classed as
Question:
Volcanoes and deep sea hydrothermal vents are both associated with sulfur-rich environments. Mount Etna is classed as a continuously degassing volcano and emissions of SO2 and H2S are around 1.5 Tg y−1 and 100 Gg y−1, respectively (Tg = 1012 g; Gg = 109 g).
(a) Draw Lewis structures for H2S and SO2, ensuring that the octet rule is obeyed by the S and O atoms. Your answer must be consistent with the fact that in SO2, the two sulfur–oxygen bonds are the same length.
(b) Are H2S and SO2 polar or non-polar molecules? If polar, draw a diagram to show the direction of the molecular dipole moment.
(c) In the troposphere, SO2 reacts with HO· radicals. Construct an MO diagram for HO· from H and O atoms, and deduce what you can about the bonding in HO·.
Step by Step Answer: