The virial coefficient can be related to the pair potential by Eqn. 7.59. (a) Derive the integrated

Question:

The virial coefficient can be related to the pair potential by Eqn. 7.59.

B = 00 2 N  (1 0 - exp(-#7)  dr kT 1- 7.59

(a) Derive the integrated expression for the second virial coefficient in terms of the square well potential parameters ε/k, σ, and R.

(b) Fit the parameters to the experimental data for argonT(K) 85 100 150 200 250 300 B (cm/mole) -251 -183.5 -86.2 -47.4 -27.9 -15.5 T(K) 400 500 600 700 800 900 B

(c) Fit the parameters to the experimental data for propane.T(K) 250 260 270 285 300 315 330 B (cm/mole) -584 -526 -478 -424 -382 -344 -313 T(K) 350 375 400 430 470 500

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For  book-img-for-question
Question Posted: