An aldohexose A is either d-idose or d-gulose (see Fig. 24.3). It is found that a different

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An aldohexose A is either d-idose or d-gulose (see Fig. 24.3). It is found that a different aldohexose, L-(2)-glucose, gives the same aldaric acid as A. What is the identity of A?

- - H  CH=0 -OH HO OH  OH -OH CHOH H H CH=0 H  -OH HO -OH H  H CHOH CH=O   H HO OH -OH CHOH H H CH=0 H -H

D-(+)-allose - -  D-(+)-altrose CH=O  OH OH CHOH D-(-)-ribose  H D-(+)-glucose D-(+)-mannose CH-O OH  CHOH

D-(-)-erythrose H CH=0 -OH CHOH D-(+)-glyceraldehyde D-(-)-threose FIGURE 24.3 The D family of aldoses. Each

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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