Quaternization (Sec. 23.6) does not occur in the reactions shown in Eqs. 23.26 and 23.27. Explain. NH

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Quaternization (Sec. 23.6) does not occur in the reactions shown in Eqs. 23.26 and 23.27. Explain. NH + HC=0 NaBH3CN HOAC CH3CN/HO EtNHCH,Ph + H,C=O benzylethylamine formaldehyde NaBH3CN CH3CN/HO KOH KOH

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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Question Posted: Dec 07, 2023 05:21 AM

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Quaternization (Sec. 23.6) does not occur in the reactions shown in Eqs. 23.26 and 23.27. Explain. NH

Question:

NH₂ + H₂C=0 NaBH3CN HOAC CH3CN/H₂O Et—NH–CH,Ph + H,C=O benzylethylamine formaldehyde NaBH3CN НОАС CH3CN/H₂O KOH KOH N(CH3)2 (84% yield) (23.26) CH3 Et-N-CH₂Ph benzylethylmethylamine (80% yield) (23.27)

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The products of Eqs 2326 and 2327 are both tertiary amines Tertiary amines form unstable ...View the full answer

Organic Chemistry

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