Consider the gas-phase isomerization of cyclopropane. Are the following data of the observed rate constant as a
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Are the following data of the observed rate constant as a function of pressure consistent with the Lindemann mechanism?
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CH, CH,CH=CH2 CH,-CH2 k (10ʻs-1) 2.98 2.82 P (Torr) 84.1 к (10'5-1) P (Torr) 1.37 1.30 0.569 0.170 0.857 0.486 34.0 2.23 11.0 6.07 2.00 0.120 0.392 0.067 2.89 1.54 0.303
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