S p hybridization on each Ge atom in planar trans-digermane has been described as sp 1.5

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S − p hybridization on each Ge atom in planar trans-digermane has been described as sp1.5 for the Ge―Ge sigma bond and sp1.8 for the Ge―H bond. Suppose that the Ge lone electron (in terms of Lewis dot valence electrons) is in an spn hybrid orbital, where n is the hybrid’s p character. The three in-plane s-p hybrid orbitals on germanium must be normalized and mutually orthogonal. Assume that the molecule lies in the xz plane with the Ge―Ge bond on the z axis. Express the hybrid orbitals as linear combinations of the p and s AOs and calculate the coefficients. Use these values to calculate n.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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