This problem explores under what conditions the classical limit is reached for a macroscopic cubic box of

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This problem explores under what conditions the classical limit is reached for a macroscopic cubic box of edge length a. A nitrogen molecule of average translational energy 3/2kBT is confined in a cubic box of volume V = 1.250 m3 at 298 K. Use the result from Equation (15.25) for the dependence of the energy levels on a and on the quantum numbers nx ,ny , and nz

a. What is the value of the “reduced quantum number” a = √n2x + n2y + n2z for T = 298 K?

b. What is the energy separation between the levels α and α + 1? (Hint: Subtract Ε α +1 from Ε α before plugging in numbers.)

c. Calculate the ratio E α + 1 – E α /kBT and use your result to conclude whether a classical or quantum mechanical description is appropriate for the particle.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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