FIGURE P29.64 shows a mass spectrometer, an analytical instrument used to identify the various molecules in a sample by measuring their charge-to-mass ratio q/m. The sample is ionized, the positive ions are accelerated (starting from rest) through a potential difference Δ­V, and they then enter a region of uniform magnetic field. The field bends the ions into circular trajectories, but after just half a circle they either strike the wall or pass through a small opening to a detector. As the accelerating voltage is slowly increased, different ions reach the detector and are measured. Consider a mass spectrometer with a 200.00 mT magnetic field and an 8.0000 cm spacing between the entrance and exit holes. To five significant figures, what accelerating potential differences Δ­V are required to detect the ions (a) O₂⁺, (b) N⁺₂,(c) CO⁺? 

See Exercise 29 for atomic masses; the mass of the missing electron is less than 0.001 u and is not relevant at this level of precision. Although N₂⁺ and CO⁺ both have a nominal molecular mass of 28, they are easily distinguished by virtue of their slightly different accelerating voltages. Use the following constants: 1 u = 1.6605 × 10^-27 kg, e = 1.6022 × 10^-19 C.

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Δν Detector FIGURE P29.64