(a) Write the electronic configuration of the complex (Fe(NH3)6]3* on the basis of Ligand Field theory...

  

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(a) Write the electronic configuration of the complex (Fe(NH3)6]3* on the basis of Ligand Field theory and draw the MO diagram. (b) Predict whether a reaction will occur when Br is added to aqueous solution of each of the following complex ions. Explain. i. (FeF ii. [Pt(NH3)31]* (b) Using the criterion of number of product particles, predict which of the following will be more favored in terms of AS° reaction: i. [Cu(NH3)41?* (aq) +4H20 (1) -- [Cu(H20),12* (aq) + 4NH3(aq) K, for [Cu(NH3)42 = 1.7 x 1013 ii. [Cu(en),12* (aq) +4H20 (1) (Cu(H20)4]2* (aq) + 2en(aq) K, for [Cu(en),2 = 1.0 x 1020 (a) Write the electronic configuration of the complex (Fe(NH3)6]3* on the basis of Ligand Field theory and draw the MO diagram. (b) Predict whether a reaction will occur when Br is added to aqueous solution of each of the following complex ions. Explain. i. (FeF ii. [Pt(NH3)31]* (b) Using the criterion of number of product particles, predict which of the following will be more favored in terms of AS° reaction: i. [Cu(NH3)41?* (aq) +4H20 (1) -- [Cu(H20),12* (aq) + 4NH3(aq) K, for [Cu(NH3)42 = 1.7 x 1013 ii. [Cu(en),12* (aq) +4H20 (1) (Cu(H20)4]2* (aq) + 2en(aq) K, for [Cu(en),2 = 1.0 x 1020

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