The figure below shows the schematic polarization (P) versus electric field (E) curve for a ferroelectric material.
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Question:
The figure below shows the schematic polarization (P) versus electric field (E) curve for a ferroelectric material.
(a) Schematically show what the polarisation (P) versus electric field (E) curve for a ferroelectric material looks like slightly above the Curie temperature for the material? Explain.
(b) BaTiO3, with a perovskite-type structure is ferroelectric at room temperature. Explain the structural origin for ferroelectricity in this material.
(c) Is the room temperature structure of BaTiO3 centrosymmetric or noncentrosymmetric? Explain.
(d) How does the structure of BaTiO3 change above the Curie temperature and how does that influence the ferroelectric property?
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