The molar susceptibility mol of the Prussian-blue CsFe[Cr(CN) 6 ] Curie paramagnet is 0.0163 emu/mol at

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The molar susceptibility χmol of the Prussian-blue CsFe[Cr(CN)6] Curie paramagnet is 0.0163 emu/mol at 300 K and 0.0094 emu/mol at 200 K (CGSem). Using the CGSem formula μeff = 2.828√C in Bohr magnetons per formula unit, the Curie law C = χT, and the spin-only as well as ge = 2 approximation, determine the spin state of Fe2+.

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Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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