Treatment of a 3-acylindole with LiAlH 4 in (CH3CH2)2O reduces the carbonyl all the way to a
Question:
Treatment of a 3-acylindole with LiAlH4 in (CH3CH2)2O reduces the carbonyl all the way to a CH2 group. Explain by a plausible mechanism.
Transcribed Image Text:
CR Excess LIAIH, (CH,CH,),0, A CH,R OH LIAIH, (Compare CR -C-R) H H
Fantastic news! We've Found the answer you've been seeking!
Step by Step Answer:
Answer rating: 91% (12 reviews)
O 11 CR OLI ...View the full answer
Answered By
Vidyasagar KUSHWAHA
Presentl i have been cleared CSIR NET/JRF examination which is cetral level exam .I have also written IIT GATE examination whose result in waiting till now.
I have been granted CSIR JRF and now i am preparing for interview for Ph.D. admission
0.00
0 Reviews
10+ Question Solved
Related Book For
Organic Chemistry structure and function
ISBN: 978-1429204941
6th edition
Authors: K. Peter C. Vollhardt, Neil E. Schore
Question Posted:
Students also viewed these Sciences questions
-
The commercial synthesis of a useful heterocyclic derivative requires treatment of a mixture of aldopentoses (derived from corncobs, straw, etc.) with hot acid under dehydrating conditions. The...
-
Carboxylic acids having a second carbonyl group two atoms away lose CO2 (decarboxylate.) through an intermediate enolate ion when treated with base. Write the mechanism of this decarboxylation...
-
Proteins can be cleaved specifically at the amide bond on the carboxyl side of methionine residues by reaction with cyanogen bromide, BrC = N. The reaction occurs in several steps: (a) The first step...
-
M/s Active Builders Ltd. invested in the shares of another company (with an intention to hold the shares for short term period )on 31st October, 2016 at a cost of Rs.4,50,000. It also earlier...
-
(i) In the model with one endogenous explanatory variable, one exogenous explanatory variable, and one extra exogenous variable, take the reduced form for y2, (15.26), and plug it into the structural...
-
textbook lists five components necessary for effective auditing and monitoring of risk management and governance processes. Explain the components and identify a relevant or applicable AICPA Code for...
-
Use the working papers from Application Problem 20-2 to complete this problem. Instructions: Prepare a statement of cost of goods manufactured for Cramer Corporation. The statement is for the month...
-
Wheeler Bus Lines uses the units-of-activity method in depreciating its buses. One bus was purchased on January 1, 2014, at a cost of $145,000. Over its 4-year useful life, the bus is expected to be...
-
There is a common misconception that labour is the main factor affecting productivity and that working harder is equivalent to higher productivity. However there are also various other factors which...
-
22) 3 = log (5 - x) A) X = -3 23) log6 x + log6 (x + 5) = 2 A) X = 1 B) X = -3, 3 B) X = -9 7 ax-1/2 = C) x = 4 D) X = -5,1 D) X = 1, X = -6
-
Heterocycle C, C 5 H 6 O, exhibits 1 H NMR spectrum C and is converted by H 2 and Raney nickel into compound D, C 5 H 10 O, with spectrum D. Identify compounds C and D. (Note: The coupling constants...
-
The sequence in the margin is a rapid synthesis of one of the heterocycles in this chapter. Draw the structure of the product, which has 1 H NMR spectrum F. 'H NMR 1 H 1 H 3 H 1H. 9.2 8.5 8.4 7.9 7.8...
-
A fair coin (i.e., heads and tails are equally likely) is tossed three times. Let X be the number of heads observed in three tosses of this fair coin. a. Find the probability distribution of X. b....
-
Do you believe that sport management theory is or should be as precise as physics or chemistry? Explain your answer.
-
For the companies you listed in question 6, identify their methods of going global.
-
Categorize a few sport companies you are familiar with as international or multinational.
-
Give examples of other functional departments.
-
Why would a sport organization use a focus strategy rather than try to appeal to all customers?
-
How does systematic study contribute to our understanding of OB?
-
A new car sold for $31,000. If the vehicle loses 15% of its value each year, how much will it be worth after 10 years?
-
The following 1H NMR spectrum is that of an alcohol, C8H10O. Propose a structure. TMS 6. Chemical shift (8) 3 O ppm 10 8. Intensity
-
Propose structures for alcohols that have the following 1H NMR spectra: (a) C5H12O (b) C8H10O Part (a) TMS O ppm 10 3 2 Chemical shift (8) Part (b) TMS O ppm 10 8. 6. 4 3 2 Chemical shift (8) Inten
-
Propose structures for alcohols that have the following 1H NMR spectra: (a) C9H12O (b)C8H10O2 Part (a) TMS 10 O ppm Chemical shift (8) Part (b) TMS O ppm 10 8. Chemical shift (8) Intensity Intensity...
-
Unlike the United States, many countries grant their banks the authority to: make equity investments in businesses. take deposits. form bank holding companies. lend to foreign companies and...
-
Information about three securities appears next. Beginning-of-Year Price Interest/Dividend End-of-Year Price Stock 1 Stock 2 $ 44.20 Bond 1 $ 2.95 $ 1,190 $ 48.45 $ 3.18 Paid $ 3.20 $ .00 $ 1,218 $...
-
( The Zero - beta CAPM. ) Consider a two - period economy with per - fect financial markets, where three risky assets in positive net supply are traded at date 0 , and assets generate cash flows at...
Study smarter with the SolutionInn App