Consider the full data set in Table 6.5 for the reversible reaction between sulfuric acid and diethyl sulfate and test the applicability of each of the following rate expressions:

Table 6.5

Concentration of H2SO4 versus time for the reaction of sulfuric acid with diethyl sulfate in aqueous solution at 22.9◦C, full data
set. Data of Hellin and Jungers, Bull. Soc. Chim. France, No. 2, pp. 386–400 (1957).

Transcribed Image Text:

TAKICACB, = a. b. TAKICA, = C. TA- = k₁1CA, - = K₂CM TA+ = TA+ = K₂CM TA+ = K₂CM².