A quality control technician needs to determine the percentage of arsenic (As) in a particular pesticide. The

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A quality control technician needs to determine the percentage of arsenic (As) in a particular pesticide. The pesticide is dissolved, and all of the arsenic present is converted to arsenate ions (AsO3-). Then the amount of AsO3- is determined by titrating with a solution containing silver ions (Ag+). The silver reacts with the arsenate according to the following net ionic equation:

3 Ag+ (aq) + AsO4 (aq)  Ag-AsO4(s)


When a 1.22-g sample of pesticide was analyzed this way, it required 25.0 mL of 0.102 M Ag+ solution to precipitate all of the AsO4 3-. What was the mass percentage of arsenic in the pesticide?

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Chemistry For Engineering Students

ISBN: 9780357026991

4th Edition

Authors: Lawrence S. Brown, Tom Holme

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