According to Gmehling et al. (1994),23 the system acetone + water shows azeotropes at: (1) 2793 mmHg,

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According to Gmehling et al. (1994),23 the system acetone + water shows azeotropes at: (1) 2793 mmHg, 95.1 mol% acetone, and 100°C; and (2) 5155 mmHg, 88.4 mol% acetone and 124°C. What azeotropic pressures and compositions does UNIFAC indicate at 100°C and 124°C? Othmer et al. (1946) (cf. Gmehling24) have studied this system at 2570 mmHg. Prepare T-x-y or P-x-y plots comparing the UNIFAC predictions to the experimental data.

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