Assume that the equation of state for a gas can be written in the form P(V m

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Assume that the equation of state for a gas can be written in the form P(Vm − b(T)) = RT. Derive an expression for β = 1/V (∂V /∂T)P and κ = −1/V (∂V /∂P)T for such a gas in terms of b(T), db(T)/dT, P, and Vm.

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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