The standard entropy of Pb(s) at 298.15 K is 64.80 J K -1 mol - 1 .

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The standard entropy of Pb(s) at 298.15 K is 64.80 J K-1mol-1. Assume that the heat capacity of Pb(s) is given by

Cp (Pb,s) J mol- K- T 22.13 + 0.01172+1.00 x 10-3 K !! K?

The melting point is 327.4°C and the heat of fusion under these conditions is 4770. J mol-1. Assume that the heat capacity of Pb(l) is given by

a. Calculate the standard entropy of Pb(l) at 725°C.

b. Calculate ΔH for the transformation Pb(s, 25.0°C) †’ Pb(l, 725°C).

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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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