For borates with similar orientation of the BO 3 groups, the NLO coefficients should roughly scale with
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For borates with similar orientation of the BO3 groups, the NLO coefficients should roughly scale with the coplanar character and density of the BO3 groups. The following
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borates have highly coplanar anions: -BaBO4 (R3c, unit-cell volume 1731 , Z = 18), Sr Be(BO3)0 (P6c2, unit-cell volume 290.8 , Z = 2), KBeBO3F (R32, unit-cell volume 318.0 , Z = 3). (a) Calculate the concentration of BO3 groups per unit volume for each compound. (b) The largest NLO coefficients for each compound are the d22 = 2.3 pm/V for B-BaB2O4, d1 = 1.52 pm/V for SrBe(BO3)20 and d1 = 0.8 pm/V for KBBO3F. Do the NLO coefficients scale with the concentration of BO3 groups? (c) CsBe BO3F2 (C2, unit-cell volume 243 , Z = 2) also has nearly coplanar BO3 groups. How would you expect its NLO coefficients to compare with the other three compounds?
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a In BaB04 each B306 polyatomic ion contains three BO3 groups The simplest way to ...View the full answer
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Related Book For
Solid State Materials Chemistry
ISBN: 9780521873253
1st Edition
Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt
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