30 mol/s of hydrogen gas and 15 mol/s of air, each compressed to 25 bar, enter a steady state reactor as shown in Figure 15-5, where the nitrogen in the air reacts with the hydrogen to form ammonia:

N₂ + 3H₂ ↔2NH₃ 

The stream leaving the reactor is at equilibrium at a temperature of 300°C. It is then cooled (though it remains at 25 bar) and sent to a vessel in which the liquid and vapor are separated from each other. The liquid ammonia is the desired product. Find the flow rate of liquid product and the composition and flow rate of the vapor stream for the following.  

A. The streams leaving the separator are in VLE at 25°C. 

B. The streams leaving the separator are in VLE at 0°C. Model air as 79 mol% nitrogen and 21 mol% oxygen, model all gas/vapor phases as ideal, and assume the liquid product is pure ammonia (in other words, nitrogen, oxygen, and hydrogen are modeled as gases that are insoluble in ammonia). 

There is no catalyst in the separator, so it can be assumed the reaction occurs in the reactor only.

Transcribed Image Text:

Air, P = 25 bar H₂, P = 25 bar Reactor 300°C Vapor out: N2, H₂, O2, NH3 Separator Product: Liquid NH3 FIGURE 15-5 Schematic of ammonia synthesis process described in Example 15-5.