Reaction of Fe(CO) 5 with Na 2 [Fe(CO) 4 ] in THF gives a salt Na 2

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Reaction of Fe(CO)5 with Na2[Fe(CO)4] in THF gives a salt Na2[A] and CO. The Raman spectrum of [Et4N]2[A] shows an absorption at 160 cm−1 assigned to an unbridged Fe–Fe bond. Suggest an identity and structure for [A]2−.

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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