Values of oct for [Ni(OH 2 ) 6 ] 2+ and high-spin [Mn(OH 2 ) 6
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Values of Δoct for [Ni(OH2)6]2+ and high-spin [Mn(OH2)6]3+ have been evaluated spectroscopically as 8500 and 21000 cm−1 respectively. Assuming that these values also hold for the corresponding oxide lattices, predict whether NiIIMn2IIIO4 should have the normal or inverse spinel structure. What factors might make your prediction unreliable?
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To predict whether NiIIMnIIIO4 should have the normal or inverse spinel structure based on the given values of oct the crystal field splitting parameter for NiOH262 and highspin MnOH263 we need to und...View the full answer
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