PbO adopts the tetragonal litharge structure that can be described as a distorted variant of the CsCl

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PbO adopts the tetragonal litharge structure that can be described as a distorted variant of the CsCl structure:

b a CsCl structure SOJT distortion litharge structure

The SOJT distortion driven by Pb+ leads to a large displacement of the cation toward a square face of the

Equation 5.18

dy = R - Bln vy

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Related Book For  answer-question

Solid State Materials Chemistry

ISBN: 9780521873253

1st Edition

Authors: Patrick M. Woodward, Pavel Karen, John S. O. Evans, Thomas Vogt

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