Question: (a) Heating d-altrose with dilute acid produces a nonreducing anhydro sugar (C6H10O5). Methylation of the anhydro sugar followed by acid hydrolysis yields 2, 3, 4-tri-O-methyl-
(a) Heating d-altrose with dilute acid produces a nonreducing anhydro sugar (C6H10O5). Methylation of the anhydro sugar followed by acid hydrolysis yields 2, 3, 4-tri-O-methyl- D-altrose. The formation of the anhydro sugar takes place through a chair conformation of β-D-altropyranose in which the --CH2OH group is axial. What is the structure of the anhydro sugar, and how is it formed?
(b) D-Glucose also forms an anhydro sugar but the conditions required are much more drastic than for the corresponding reaction of D-altrose. Explain.
(b) D-Glucose also forms an anhydro sugar but the conditions required are much more drastic than for the corresponding reaction of D-altrose. Explain.
Step by Step Solution
★★★★★
3.34 Rating (163 Votes )
There are 3 Steps involved in it
1 Expert Approved Answer
Step: 1 Unlock
a The anhydro sugar is formed when the axial CH 2 OH group reacts ... View full answer
Question Has Been Solved by an Expert!
Get step-by-step solutions from verified subject matter experts
Step: 2 Unlock
Step: 3 Unlock
Document Format (1 attachment)
877-C-O-S (992).docx
120 KBs Word File
