For each molecule in Problem 32, estimate the energy difference between the most stable and next best conformation Calculate the approximate ratio of the two at 300 K Problem 32 (a) cyclohexanol (b) trans 3 methylcyclohexanol (see structures in the margin) (c) cis 1 methyl 3 (1 methylethyl)cyclohexane (d) trans 1 ethyl 3 methoxycyclohexane (see structure in the margin) (e) trans 1 chloro 4 (1,1 dimethylethyl)cyclohexane Cyclohexanol CH3 trans 3 Methylcyclohexanol CH CH OCH3 trans 1 Ethyl 3 methoxycyclohexane

Question: For each molecule in Problem 32, estimate the energy difference between the most stable and next best conformation. Calculate the approximate ratio of the two

For each molecule in Problem 32, estimate the energy difference between the most stable and next best conformation. Calculate the approximate ratio of the two at 300 K.
Problem 32:
(a) cyclohexanol;

(b) trans-3-methylcyclohexanol (see structures in the margin);

(e) trans-1-chloro-4-(1,1-dimethylethyl)cyclohexane.

Cyclohexanol CH3 trans-3-Methylcyclohexanol CH CH OCH3 trans-1-Ethyl-3-methoxycyclohexane

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a Let us consider the following conformations The G value for axial to equatorial is 094 kcalmol So the energy difference will be 094 kcalmol We know ... View full answer

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