For each molecule in Problem 32, estimate the energy difference between the most stable and next best

Question:

For each molecule in Problem 32, estimate the energy difference between the most stable and next best conformation. Calculate the approximate ratio of the two at 300 K.
Problem 32:
(a) cyclohexanol;

(b) trans-3-methylcyclohexanol (see structures in the margin);

(e) trans-1-chloro-4-(1,1-dimethylethyl)cyclohexane.

Fantastic news! We've Found the answer you've been seeking!

Step by Step Answer:

Related Book For book-img-for-question

Organic Chemistry structure and function

ISBN: 978-1429204941

6th edition

Authors: K. Peter C. Vollhardt, Neil E. Schore

See More Books

Question Posted: Jul 15, 2016 06:51 AM

See More Questions

For each molecule in Problem 35, describe the orbitals that are used to form every bond to each of the indicated atoms (atomic s, p, hybrid sp, sp2, or sp3).
On viewing the drawings of cis- and trans-decalin in Figure 4-13, which do you think is the more stable isomer? Estimate the energy difference between the two isomers.
Electronic excitation of a molecule may weaken or strengthen some bonds because bonding and antibonding characteristics differ between the HOMO and the LUMO. For example, a carbon-carbon bond in a...
Figure 6.6 shows the derivative g'. If g(0) = 0, graph g. Give (x, y)-coordinates of all local maxima and minima. -g'(x)- 2 6. -1 Figure 6.6 5
What are the components or stages in the professional venture investing cycle after funds have been raised until closure?
Current mobile devices offer Everything from ordering a pizza to playing video games to doing your banking . IS having this consumer control and access a benefit or are We ceding some control over to...
In March 2015, a Nielsen global online survey "found that consumers are increasingly willing to pay more for socially responsible products." Over 30,000 people in 60 countries were polled about their...
Two items are omitted from each of the following three lists of cost of goods manufactured statement data. Determine the amounts of the missing items, identifying them byletter. 2,000 12,000 Work in...
Explain why special events have arisen in human civilization, why they are so popular, and how they contribute to community development and benefit stakeholders and host communities. Describe the...
1. Why do you think the regions are not responding to Wilkess initiative for change? What did Wilkes do wrong with respect to implementing the change? 2. Should Wilkes solicit more active support...
Draw the most stable conformation for each of the following substituted cyclohexanes; then, in each case, flip the ring and redraw the molecule in the higher energy chair conformation: (a)...
Sketch a potential-energy diagram (similar to mat in Figure 4-9) for methylcyclohexane showing the two possible chair conformations at the left and right ends of the reaction coordinate for...
Near the end of its scal year, a not-for-prot university was awarded a $2 million National Science Foundation grant to conduct biological research. Yet, consistent with GAAP, the college made no...
Calculate the Direct RN to Patient Ratio for the Neuro unit using the following information. Required data is included in the shaded boxes. Critical Thinking Exercise Table to Calculate RN to Patient...
Which one of the following is not a good reason to hire a contingent worker? a. To fill in for absent employees b. Keeping employees for shorter periods of time keeps salary costs low c. To...
Calculate the HPPDs for each of the following Telemetry unit Hours Classifications for one pay period of 14 days. The Budget Average Daily UOS is 20 and the pay period total is 280. Required data is...
Please complete the calculations in the Direct Care Variable Staffing Plan table to maintain the budget direct, RN and NA HPPD and Target direct caregiver ratios for each level of census between 25...
Ethnocentrism is a belief that a. ethics are central to doing well in business. b. the value of commerce changes in different societies. c. all cultures should be respected equally. d. can lead to...
Solve the following simultaneous equations. x 2y = 1 4y 2 3y 2 = 1
Determine the center and radius of each circle. Sketch each circle. 4x 2 + 4y 2 9 = 16y
Dehydration of 2, 2, 3, 4, 4-pentamethyl-3-pentanol gave two alkenes A and B. Ozonolysis of the lower boiling alkene A gave formaldehyde (CH2 = O) and 2, 2, 4, 4-tetramethyl-3-pentanone. Ozonolysis...
Compound A (C7H13Br) is a tertiary bromide. On treatment with sodium ethoxide in ethanol, A is converted into B (C7H12). Ozonolysis of B gives C as the only product. Deduce the structures of A and B....
East Indian sandalwood oil contains a hydrocarbon given the name santene (C9H14). Ozonation of santene followed by hydrolysis gives compound A. What is the structure of santene?
" a practitioner is never finished contracting "... What do you think are some of the challenges are when re-contracting, when situations change, and how would you respond?
Give a brief description of a product launch for any business firm/organization that you want to open or would want to work with in future. Provide at least two appropriate 'Call to Actions' for the...
Briefly explain the organizational pattern of a 'Feature Article'? Why is 'tension' so important in a Feature article?

For each molecule in Problem 32, estimate the energy difference between the most stable and next best

Question:

он Cyclohexanol он CH3 trans-3-Methylcyclohexanol CH CH OCH3 trans-1-Ethyl-3-methoxycyclohexane

Step by Step Answer:

a Let us consider the following conformations The G value for axial to equatorial is 094 kcalmol So the energy difference will be 094 kcalmol We know ...View the full answer

Organic Chemistry structure and function

Students also viewed these Organic Chemistry questions