Question: For gases, the canonical partition function, Q, is related to the molecular partition function q by Q = q NIN!. Use the expression for q

For gases, the canonical partition function, Q, is related to the molecular partition function q by Q = q NIN!. Use the expression for q and general thermodynamic relations to derive the perfect gas law P V = I1RT.

Step by Step Solution

★★★★★

3.44 Rating (173 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer

Step: 1 Unlock

ame pkT KT 173 TN a In qN av 1645b ... View full answer

Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock

Step: 3 Unlock

Document Format (1 attachment)

57-C-PC-S (316).docx

120 KBs Word File

Students Have Also Explored These Related Physical Chemistry Questions!

What is the difference between an information system and a computer application?

Derive relations for (a) u. (b) h. (c) s of a gas that obeys the equation of state (P + a/v2)v = RT for an isothermal process.

Use Gauss's law to derive an expression for the electric field outside the thin spherical shell of Conceptual Example 16.8.

Derive an expression for the moment- generating function of a Rayleigh random variable whose PDF is f(x) = xexp(-2)11(x)

P13D.1* For a perfect gas, the canonical partition function, Q, is related to the molecular partition function g by Q=qN/N!. In Topic 13F it is established that p = kt( ln QlaV),. Use the expression...

A psychologist conducts a survey of students to determine whether juniors' and seniors' scores differ on a statistics exam (scored on a 0 to 100 scale). To do so, she collected scores for a sample of...

ENSURE WORK IS ORIGINAL OR I REJECT AND REPORT YOU TON THE SUPPORT INSTANTLYThe end result does now not should be taken care of. You may additionally expect n 6 length(xs). [Hint: Function least is a...

Make sense of the thoughts of static and dynamic chains, giving an illustration of a circumstance in which they contrast (for example reference to some unacceptable one would get to the wrong...

For ideal gases, the canonical partition function can be related to the molecular partition function such that Q = q N N ! . To account for intermolecular interactions, J . D . van der Waals proposed...

the chemical potential, \ mu , is related to the canonical partition function, Q , by the following relationship: \ mu ( T , p ) = - kT ( lnQ / N ) . Consider a cubic box with an edge length L...

What is required for a N - particle canonical partition function Q to be related to the molecular partition function q by Q = q N N ! ? Be specific about the requirements for both the numerator and...

Let f(x) be a continuous function with f(4) = 3, f'(4) = 5 and f"(4) = -9. a) Find the equation of the tangent line to h(x)= 2f(x)+7 at x 4. increasing or decreasing at x 4? f(x) b) Is g(x) = c) Find...

Give an example of each of the four levels of power discussed in this chapter. Also, give an example of each of the spheres of business power.

05.01-PR019 Tempura, Inc., is considering two projects. Project A requires an investment of $50,000. Estimated annual receipts for 20 years are $20,000; estimated annual costs are $12,500. An...

Explain what is meant by a digital firm and state two advantages of a digital firm. Support answer using examples.

What are the task dependencies for designing a global chat service?

A bullet moving at the rate of 300 m/s is fired into a thick target and penetrates up to 500 mm. If it is fired into a 250 mm thick target, find the velocity of emergence. Take the resistance to be...

write a java gui program to convert binary,decimal

CA1.1 (LO 1) (IFRS and Standard-Setting) Presented below are five statements to identify as true or false. If false, explain why the statement is incorrect. 1. IFRS is the term used to indicate the...

The Haber process for the synthesis of ammonia is one of the most significant industrial processes for the well-being of humanity. It is used extensively in the production of fertilizers as well as...

Use Internet resources to identify the magnetic character at room temperature (diamagnetic, paramagnetic, ferromagnetic, antiferromagnetic) of as many d-block elements as you can.

A unit cell for the calcite structure can be found at http://webmineral.com. From this structure, identify (a) The crystal system and (b) The number of formula units present in the unit cell.

There are two separate questions to solve; i) closing entries, and ii) preparing financial statements. 1) Given the following adjusted account balances in random order, prepare the closing entries...

Which of the following is not part of a company's optimal capital structure that maximizes its stock price? a . Common equity b . Debt c . Preferred stock d . Long - term assets

Portfolio Return Year-to-date, Company O had earned a -3.20 percent return. During the same time period, Company V earned 9.1 percent and Company M earned 7.35 percent If you have a portfolio made up...