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In each of the following indicate which reaction will occur faster. Explain your reasoning. (a) CH3CH2CH2CH2Br or CH3CH2CH2CH2I with sodium cyanide in dimethyl sulfoxide (b)
In each of the following indicate which reaction will occur faster. Explain your reasoning.
(a) CH3CH2CH2CH2Br or CH3CH2CH2CH2I with sodium cyanide in dimethyl sulfoxide
(b) 1-Chloro-2-methylbutane or 1-chloropentane with sodium iodide in acetone
(c) Hexyl chloride or cyclohexyl chloride with sodium azide in aqueous ethanol
(d) Solvolysis of 1-bromo-2,2-dimethylpropane or tert-butyl bromide in ethanol
(e) Solvolysis of isobutyl bromide or sec-butyl bromide in aqueous formic acid
(f) Reaction of 1-chlorobutane with sodium acetate in acetic acid or with sodium methoxide in methanol
(g) Reaction of 1-chlorobutane with sodium azide or sodium p-toluenesulfonate in aqueous ethanol
(a) CH3CH2CH2CH2Br or CH3CH2CH2CH2I with sodium cyanide in dimethyl sulfoxide
(b) 1-Chloro-2-methylbutane or 1-chloropentane with sodium iodide in acetone
(c) Hexyl chloride or cyclohexyl chloride with sodium azide in aqueous ethanol
(d) Solvolysis of 1-bromo-2,2-dimethylpropane or tert-butyl bromide in ethanol
(e) Solvolysis of isobutyl bromide or sec-butyl bromide in aqueous formic acid
(f) Reaction of 1-chlorobutane with sodium acetate in acetic acid or with sodium methoxide in methanol
(g) Reaction of 1-chlorobutane with sodium azide or sodium p-toluenesulfonate in aqueous ethanol
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a b The reaction conditions are typical for an SN2 process The methyl branch in 1chloro 2methylbutane sterically hinders attack at C1 The unbranched i...
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