In an elementary chemical reaction, single molecules of two reactants A and B form a molecule of

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In an elementary chemical reaction, single molecules of two reactants A and B form a molecule of the product C: A + B → C. The law of mass action states that the rate of reaction is proportional to the product of the concentrations of A and B:


d[C] K[A][B] dt

(See Example 4 in Section 3.3) Thus, if the initial concentrations are [A] = a moles/L and [B] b moles/L and we write x = [C], then we have dx/dt = k (a €“ x) (b €“ x)
(a) Assuming that a ≠ b, find as a function of t. Use the fact that the initial concentration of C is 0.
(b) Find x(t) assuming that a = b. How does this expression for x(t) simplify if it is known that [C] = a/2 after 20 seconds?
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Physical Chemistry

ISBN: 978-0321812001

3rd edition

Authors: Thomas Engel, Philip Reid

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