In the previous problem and the associated molecular model at the book's website, you considered the role
Question:
(a) What is the LUMO in an SN1 reaction and in what reactant and species is it found?
(b) Open the molecular model at the book's website titled "Isopropyl Methyl Ether Carbocation LUMO." Identify the lobe of the LUMO in this carbocation model with which a nucleophile would interact.
(c) Open the model titled "Isopropyl Methyl Ether Carbocation HOMO." Why is there a large orbital lobe between the oxygen and the carbon of the carbocation?
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a The LUMO in an S N 1 reaction is the orbital that includes the vacant p orbital in our simplified ...View the full answer
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Related Book For 
Organic Chemistry
ISBN: 978-1118133576
11th edition
Authors: Graham Solomons, Craig Fryhle, Scott Snyder
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