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In the simplest molecular orbital treatment of conjugated systems, it is assumed that the system does not interact with the framework of bonds. When this

In the simplest molecular orbital treatment of conjugated systems, it is assumed that the π system does not interact with the framework of σ bonds. When this MO method was used to calculate the charge distribution in cyclohexadienyl cation, it gave the results indicated. How does the charge at each carbon compare with that deduced by examining the most stable resonance structures for cyclohexadienyl cation?

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The three most stable resonance structures for cyclohexadienyl cation are H H HH H H H H HH ... blur-text-image
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