J.J Dannenberg, D. Leotard, P. Hal Vick, and I.C. Rayez (J. Phys. Chem. 100, 9631 (996)) carried

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J.J Dannenberg, D. Leotard, P. Hal Vick, and I.C. Rayez (J. Phys. Chem. 100, 9631 (996)) carried out theoretical studies of organic molecules consisting of chains of unsaturated four-membered rings. The calculations suggest that such compounds have large numbers of unpaired spins, and that they should therefore have unusual magnetic properties. For example, the lowest-energy state of the five-ring compound CnH14 (4) is computed to have S = 3, but the energies of S = 2 and S = 4 structures are each predicted to be 50 k] mol:" higher in energy. Compute the molar magnetic susceptibility of these three low-lying levels at 298 K. Estimate the molar susceptibility at 298 K if each level is present in proportion to its Boltzmann's factor (effectively assuming that the degeneracy is the same for all three of these levels).



J.J Dannenberg, D. Leotard, P. Hal Vick, and I.C. Rayez

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