a. Use the data in Table 13.1-4 and the information that f G AgCl =

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a. Use the data in Table 13.1-4 and the information that ΔfG°AgCl = −108.7 kJ/mol to predict the solubility product K°AgCl of silver chloride in water, and compare your predictions with the data given in Illustration 13.3-2. 

b. Use the data in Table 13.1-4 and the information that ΔfG°TlCl = −186.02 kJ/mol to predict the solubility product K°TlCl of thallium chloride in water, and compare your predictions with the data given in Illustration 13.3-2.

Table 13.1-4

Ion Ag+ Al+++ Ba++ Ca++ CI Cs+ Cu+ Cu++ F- Fe++ Fe+++ Hg++ HSO3 HSO4 I- Af H (kJ/mol) 105.90 5470.33 -538.36

Illustration 13.3-2.

The solubility of silver chloride in water at 25°C is 1.273 × 10−5 kmol/m3, and that of thallium chloride is 0.144 kmol/m3. Estimate the simultaneous solubility of AgCl and TlCl in water. 

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