Basicity in the gas phase can be defined as the proton affinity of the base, for example,

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Basicity in the gas phase can be defined as the proton affinity of the base, for example, CH3NH2(g) + H+(g) ⇌ CH3NH3 +(g). In the gas phase, (CH3)3N is more basic than CH3NH2, while in solution the reverse is true. Explain this observation.

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