Acetone is a common solvent. (See Study Question 8 for the structure of acetone.) (a) Allyl alcohol,

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Acetone is a common solvent. (See Study Question 8 for the structure of acetone.)
(a) Allyl alcohol, CH2=CH—CH2OH, is an isomer of acetone. Acetone has a vapor pressure of 100 mm Hg at +7.7°C. Predict whether the vapor pressure of allyl alcohol is higher or lower than 100 mm Hg at this temperature? Explain.
(b) Use the Clausius–Clapeyron equation to calculate the enthalpy of vaporization of acetone from the following data.Temperature (C) Vapor Pressure (mm Hg) -9.4 40. +7.7 100. 39.5 400. 56.5 760.

(c) Fluorination of acetone, C3H6O (substitution of fluorine for H) produces a gaseous compound with the formula C3H6−xFxO. To identify this compound its molar mass was determined by measuring the gas density. The following data were obtained: Mass of gas, 1.53 g; volume of flask = 264 mL; pressure exerted by gas, 722 mm Hg; temperature, 22°C. Calculate the molar mass from this information, then identify the molecular formula.

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Chemistry And Chemical Reactivity

ISBN: 9780357001172

10th Edition

Authors: John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

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