It can be shown that the buffer capacity is where c T is the molar analytical concentration

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It can be shown that the buffer capacity is

where cT is the molar analytical concentration of the buffer.
(a) Show that

(b) Use the equation in (a) to explain the shape of Figure 7-10.
(c) Differentiate the equation presented at the beginning of the problem, and show that the buffer capacity is at a maximum when ∝0 = ∝1 = 0.5.
(d) Describe the conditions under which these relationships apply.
(e) Buffer capacity is sometime called inverse slope. Explain the origin of this term.

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Fundamentals Of Analytical Chemistry

ISBN: 9780357450390

10th Edition

Authors: Douglas A. Skoog, Donald M. West, F. James Holler, Stanley R. Crouch

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