Question: (a) [SnF 5 ] has a polymeric structure consisting of chains with cis-bridging F atoms. Draw a repeat unit of the polymer. State the

(a) [SnF₅]⁻ has a polymeric structure consisting of chains with cis-bridging F atoms. Draw a repeat unit of the polymer. State the coordination environment of each Sn atom, and explain how the overall stoichiometry of Sn : F = 1:5 is retained in the polymer.

(b) Which of the salts PbI₂, Pb(NO₃)₂, PbSO₄, PbCO₃, PbCl₂ and Pb(O₂CCH₃)₂ are soluble in water?

(c) The IR spectrum of ClCN shows absorptions at 1917, 1060 and 230 cm⁻¹. Suggest assignments for these bands and justify your answer.

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a SnF5 polymeric structure In the SnF5 polymeric structure each tin Sn atom is coordinated to five fluorine F atoms forming a chain with cisbridging F ... View full answer

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