Comment on the following observations. (a) In its complexes, Co(III) forms strong bonds to O- and N-donor

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Comment on the following observations.

(a) In its complexes, Co(III) forms strong bonds to O- and N-donor ligands, moderately strong bonds to P-donor ligands, but only weak bonds to As-donor ligands.

(b) The values of log K for the reaction:

(c) Phosphine adducts of Cr(III) halides can be prepared, but crystallographic studies reveal very long Cr–P bonds (e.g. 247 pm).

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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Question Posted: Jul 22, 2023 07:19 AM

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Comment on the following observations. (a) In its complexes, Co(III) forms strong bonds to O- and N-donor

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2+ Zn²+ (aq) + X = [ZnX]+ (aq) are 0.7 for X-F, -0.2 for X-Cl, -0.6 for X = Br, and -1.3 for X=I.

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a Observation about CoIII bonding with different donor ligands This observation is related to the concept of ligand strength and the nature of metalligand bonding In coordination complexes metal ions ...View the full answer

Inorganic Chemistry

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