Consider all 12 of the p orbitals on the four Cl atoms of a square planar complex

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Consider all 12 of the p orbitals on the four Cl atoms of a square planar complex like [PtCl₄]²⁻.

(a) Determine how these p orbitals transform under D_4h and reduce the representation.

(b) Which metal orbitals can these SALCs bond with?

(d) Which SALCs and which metal orbitals contribute to the in-plane π bonds?

(e) Which SALCs and which metal orbitals contribute to the out-of-plane π bonds?

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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Question Posted: Jul 28, 2023 02:15 AM

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Consider all 12 of the p orbitals on the four Cl atoms of a square planar complex

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a To determine how the 12 p orbitals on the four Cl atoms of PtCl42 transform under D4h symmetry we ...View the full answer

Inorganic Chemistry

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