Question: Structures 19.2219.24 show bond angle data (determined by X-ray diffraction) for some complexes with low coordination numbers. Comment on these data, suggesting reasons for deviations

Structures 19.22–19.24 show bond angle data (determined by X-ray diffraction) for some complexes with low coordination numbers. Comment on these data, suggesting reasons for deviations from regular geometries.

(Me3Si) 3 Si 111 137 Fe-CI (Me3Si) 3 Si 112 (19.22) N

83 138 Cu NCMe N 139 (19.23)

(Me3Si) 3 Si 111 137 Fe-CI (Me3Si) 3 Si 112 (19.22) N 83 138 Cu NCMe N 139 (19.23)

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