Suggest reasons for the following observations. (a) Although Pd(II) complexes with monodentate O-donor ligands are not as

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Suggest reasons for the following observations. 

(a) Although Pd(II) complexes with monodentate O-donor ligands are not as plentiful as those with P-, S- and As-donor ligands, Pd(II) forms many stable complexes with bidentate 0,0'-donor ligands. 

(b) [EDTA]4‾ forms very stable complexes with first row d-block metal ions M2+ (e.g. log K = 18.62 for the complex with Ni2+); where the M3+ ion is accessible, complexes between M3+ and [EDTA] are more stable than between the corresponding M2+ and [EDTA]4‾ (e.g. log K for the complex with Cr2+ is 13.6, and for Cr3+ is 23.4).

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Inorganic Chemistry

ISBN: 9781292134147

5th Edition

Authors: Catherine Housecroft

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