Treatment of TiCl 4 with 4 equivalents of NaCp gives a single organometallic compound (together with NaCl

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Treatment of TiCl4 with 4 equivalents of NaCp gives a single organometallic compound (together with NaCl byproduct). At room temperature the 1H-NMR spectrum shows a single sharp singlet; on cooling to −40°C this singlet separates into two singlets of equal intensity; further cooling results in one of the singlets separating into three signals with intensity ratios 1:2:2. Explain these results.

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Inorganic Chemistry

ISBN: 9780198768128

7th Edition

Authors: Mark Weller, Tina Overton, Jonathan Rourke

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