Use the Kapustinskii equation and the ionic and thermochemical radii given in Resource section 1 and Table
Question:
Use the Kapustinskii equation and the ionic and thermochemical radii given in Resource section 1 and Table 4.10, and r(Bk4+) = 96 pm to calculate lattice enthalpies of
(a) BkO2,
(b) K2SiF6,
(c) LiClO4.
Table 14.10.
Transcribed Image Text:
Main-group elements BeF² (245) Complex ions [Tif]²- 289 [TICI]² 331 [ZrCI² 358 BF 232 [PtCl]²- 313 [PtBr]² 342 CO²/ 178 CN- 191 [SIF 1²- 269 [GeF]² 265 NO, 179 NO (189) PO (238) ASO¹ (248) Sb0% (260) ISnC] 326 [SnBr.]² 363 [PbCl]² 348 OH 133 02/ 173 S0² 258 SeO² 249 TeO² (254) d-Metal oxoanions [Cro 1²- (256) [MoO ]² (254) CIO 240 BrO₂ 154 10, 182 [MnO₂] (240)
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The Kapustinskii equation is as follows Hlattice Z Z rm where Hlattice Lattice enthalpy in kJmol Pro...View the full answer
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Related Book For
Inorganic Chemistry
ISBN: 9780198768128
7th Edition
Authors: Mark Weller, Tina Overton, Jonathan Rourke
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