Question: If AÌ is the operator corresponding to the mechanical quantity A and Ï n is an eigenfunction of AÌ, such that AÌÏ n = a

If AÌ‚ is the operator corresponding to the mechanical
quantity A and ϕnis an eigenfunction of Â, such that

Âϕn = anϕn

show that the expectation value of A is equal to an if the state of the system corresponds to ϕn. See Problem 5 for the formula for the expectation value.


Problem 5

In quantum mechanics, the expectation value of a mechanical quantity is given by

SV*¼ dx (A) = S*¼ dx

where  is the operator for the mechanical quantity and ψ is the wave function for the state of the system. The integrals are over all permitted values of the coordinates of the system. The expectation value is defined as the prediction of the mean of a large number of measurements of the mechanical quantity, given that the system is in the state corresponding to ψ prior to each measurement.

For a particle moving in the x direction only and confined to a region on the x axis from x = 0 to x = a, the integrals are single integrals from 0 to a and pÌ‚x is given by („/i)ˆ‚/ˆ‚x. The wave normalized function is

лх sin a a

Normalization means that the integral in the denominator of the expectation value expression is equal to unity.

SV* dx (A) = S* dx sin a a

Step by Step Solution

3.24 Rating (162 Votes )

There are 3 Steps involved in it

1 Expert Approved Answer
Step: 1 Unlock

A Son dx ... View full answer

blur-text-image
Question Has Been Solved by an Expert!

Get step-by-step solutions from verified subject matter experts

Step: 2 Unlock
Step: 3 Unlock

Students Have Also Explored These Related Mathematics Physical Chemistry Questions!