Using perturbation theory, derive the following expression for the matrix element pertinent to radiationless relaxation. How does

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Using perturbation theory, derive the following expression for the matrix element pertinent to radiationless relaxation.

How does this result compare to the vibronic coupling responsible for activation of nominally forbidden electronic transitions? Does this problem explain how the neglect of the matrix element

might be justified?

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Molecular Spectroscopy

ISBN: 9781466586598

2nd Edition

Authors: Jeanne L McHale

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Question Posted: Aug 23, 2023 08:12 AM

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Using perturbation theory, derive the following expression for the matrix element pertinent to radiationless relaxation. How does

Question:

(v.20.) We 8 ³aQk \aĤ₁\ el aQk E₂(Q)-E₂(Q) Y8 We

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The equations youve provided relate to the quantum mechanical treatment of molecular vibrations and electronic transitions using perturbation theory H...View the full answer

Molecular Spectroscopy

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