Complete the reactions given in Fig. P11.60 by giving the principal organic products. Indicate the stereochemistry of
Question:
Complete the reactions given in Fig. P11.60 by giving the principal organic products. Indicate the stereochemistry of the products in parts (d), (g), (h), (i), and (k).
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(a) CH3CH₂CH₂-Br+Na+ Eto- (c) H₂C (d) (e) H₂C quidem CH3 CO3H C=CH-CH3 + (CH3)₂CH-OH (solvent) C EtOH H H3C-CH=CH₂ + H₂O + Br₂ Hg(OAc)2 CH₂Cl₂ CrO3 pyridine NaBH4 (b) (f) CH3 H₂C-C-Br + tBuO- K+ CH₂CH3 tBuOH BrCH₂CH₂CH₂-HC-CH₂ + HIO4 H₂O (Hint: Periodic acid, HIO4, is a fairly strong acid.)
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This is a Williamson ether synthesis by the SN2 mechanism that gives CH3CHCHOCHCH3 ethyl propyl ether or 1ethoxypropane Na Br b A strong base with a t...View the full answer
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