Explain why the hydrogen migration shown in reaction (1) occurs readily and why the very similar migration

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Explain why the hydrogen migration shown in reaction (1) occurs readily and why the very similar migration shown in (2) does not take place even under forcing conditions. (The asterisked carbons indicate a carbon isotope present so that the rearrangement can be detected.)(1) (2) *CH CH H CH-CH // *CH H 195 C 250 C 4300 psi *CH CH T H CH=CH T *CH-H

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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