The G for ester hydrolysis of the neurotransmitter acetylcholine is 225.1 kJ mol 1 (26.0 kcal mol
Question:
The ΔG°´ for ester hydrolysis of the neurotransmitter acetylcholine is 225.1 kJ mol–1 (26.0 kcal mol–1), and the ΔG°´ for the hydrolysis of acetyl-CoA is 231.4 kJ mol–1 (27.5 kcal mol–1).
(a) Draw a free-energy diagram that shows how the ΔG°´ for the biosynthesis of acetylcholine from acetyl-CoA and choline can be derived from the ΔG°´ for these two hydrolysis reactions.
(b) What is the ΔG°´ for this biosynthetic reaction?
(c) What is the equilibrium constant for this reaction at 37°C? (2.3RT at 310K = 5.92 kJ mol–1.)
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a b To solve this problem use a method similar to the one given by Eq 2536 on text p 1316 The problem gives values for the AG of hydrolysis of acetylc...View the full answer
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