This problem describes the result that established the intrinsic preference for 1,2-addition in the reaction of hydrogen

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This problem describes the result that established the intrinsic preference for 1,2-addition in the reaction of hydrogen halides with conjugated dienes.

(a) What is the relationship between the products of 1,2- and 1,4-addition in the following reaction?(E)-HC=CH-CH-CH-CH3 + HCl

(b) How does the use of DCl change this relationship, if at all?(E)-HC=CH-CH=CH-CH3 + DCI

(c) The reaction with DCl gives mostly the kinetically controlled product. Give the structure of this product.

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Organic Chemistry

ISBN: 9781936221349

6th Edition

Authors: Marc Loudon, Jim Parise

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