(a) Express (C V /V) T as a second derivative of U and find its relation to...
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(a) Express (∂CV/∂V)T as a second derivative of U and find its relation to (∂U/∂V)T and (∂Cp/∂p)T as a second derivative of H and find its relation to (∂H/∂p)T.
(b) From these relations show that (∂CV/∂V)T =0 and (∂Cp/∂p)T =0 for a perfect gas.
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dU dq dw dH dU dw At constant volume the differentia...View the full answer
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Related Book For 
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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