C. Huang and W.P. Cheng (J. Colloid Interface Sci. 188, 270 (1997)) examined the adsorption of the
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C. Huang and W.P. Cheng (J. Colloid Interface Sci. 188, 270 (1997)) examined the adsorption of the hexacyanoferrate(III) ion, [Fe(CN)6]3−, on γ-Al2O3 from aqueous solution. They modelled the adsorption with a modified Langmuir isotherm, obtaining the following values of α at pH=6.5:
Determine the isosteric enthalpy of adsorption, ΔadsH⦵, at this pH. The researchers also reported ΔadsS⦵ =+146 Jmol−1K−1 under these conditions. Determine ΔadsG⦵.
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Related Book For
Physical Chemistry Thermodynamics And Kinetics
ISBN: 9781464124518
10th Edition
Authors: Peter Atkins, Julio De Paula
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